Lesson 1 Грамматика. Различные значения it
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TEXT 2 History of Chemistry 3804 п.з. The development of the modern scientific method was slow and arduous, but an early scientific method for chemistry began emerging among early Muslim chemists, beginning with the 9th century Persian or Arabian chemist Jābir ibn Hayyān (known as "Geber" in Europe), who is sometimes referred to as "the father of chemistry". He introduced a systematic and experimental approach to scientific research based in the laboratory, in contrast to the ancient Greek and Egyptian alchemists whose works were largely allegorical and often unintelligible. Under the influence of the new empirical methods propounded by Sir Francis Bacon and others, a group of chemists at Oxford, Robert Boyle, Robert Hooke and John Mayow began to reshape the old alchemical traditions into a scientific discipline. Boyle in particular is regarded as the founding father of chemistry due to his most important work, the classic chemistry text The Sceptical Chymist where the differentiation is made between the claims of alchemy and the empirical scientific discoveries of the new chemistry. He formulated Boyle's law, rejected the classical "four elements" and proposed a mechanistic alternative of atoms and chemical reactions that could be subject to rigorous experiment. The theory of phlogiston (a substance at the root of all combustion) was propounded by the German Georg Ernst Stahl in the early 18th century and was only overturned by the end of the century by the French chemist Antoine Lavoisier, the chemical analogue of Newton in physics; who did more than any other to establish the new science on proper theoretical footing, by elucidating the principle of conservation of mass and developing a new system of chemical nomenclature used to this day. Before his work, though, many important discoveries had been made, specifically relating to the nature of 'air' which was discovered to be composed of many different gases. The Scottish chemist Joseph Black (the first experimental chemist) and the Dutchman J. B. van Helmont discovered carbon dioxide, or what Black called 'fixed air' in 1754; Henry Cavendish discovered hydrogen and elucidated its properties and Joseph Priestley and, independently, Carl Wilhelm Scheele isolated pure oxygen. English scientist John Dalton proposed the modern theory of atoms; that all substances are composed of indivisible 'atoms' of matter and that different atoms have varying atomic weights. The development of the electrochemical theory of chemical combinations occurred in the early 19th century as the result of the work of two scientists in particular, J. J. Berzelius and Humphry Davy, made possible by the prior invention of the voltaic pile by Alessandro Volta. Davy discovered nine new elements including the alkali metals by extracting them from their oxides with electric current. British William Prout first proposed ordering all the elements by their atomic weight as all atoms had a weight that was an exact multiple of the atomic weight of hydrogen. J. A. R. Newlands devised an early table of elements, which was then developed into the modern periodic table of elements in the 1860s by Dmitri Mendeleev and independently by several other scientists including Julius Lothar Meyer. The inert gases, later called the noble gases were discovered by William Ramsay in collaboration with Lord Rayleigh at the end of the century, thereby filling in the basic structure of the table. Organic chemistry was developed by Justus von Liebig and others, following Friedrich Wöhler's synthesis of urea which proved that living organisms were, in theory, reducible to chemistry. Other crucial 19th century advances were; an understanding of valence bonding (Edward Frankland in 1852) and the application of thermodynamics to chemistry (J. W. Gibbs and Svante Arrhenius in the 1870s). TEXT 3 Mikhail Vasilyevich Lomonosov 5505 п.з. Mikhail Vasilyevich Lomonosov (November 19, 1711 – April 15, 1765) was a Russian polymath, scientist and writer, who made important contributions to literature, education, and science. Among his discoveries were the atmosphere of Venus and the Law of Mass Conservation in chemical reactions. His spheres of science were natural science, chemistry, physics, mineralogy, history, art, philology, optical devices and others. Lomonosov was also a poet and influenced the formation of the modern Russian literary language. In 1730, at nineteen, Lomonosov went to Moscow on foot, because he was determined to study. Not long after arriving, Lomonosov obtained admission into the Slavic Greek Latin Academy. Lomonosov lived on three kopecks a day, eating only black bread and kvass, but he made rapid progress scholastically. After three years in Moscow he was sent to Kiev to study for one year at the Kyiv-Mohyla Academy. He quickly became dissatisfied with the education he was receiving there, and returned to Moscow several months ahead of schedule, resuming his studies there. He completed a twelve-year study course in only five years, graduating at the top of his class. In 1736, Lomonosov was awarded a scholarship to St. Petersburg Academy. He plunged into his studies and was rewarded with a two-year grant to study abroad at the University of Marburg, in Germany. The University of Marburg was among Europe's most important universities in the mid-18th century due to the presence of the philosopher Christian Wolff, a prominent figure of the German Enlightenment. Lomonosov became one of Wolff's personal students while at Marburg. Both philosophically and as a science administrator, this connection would be the most influential of Lomonosov's life. Between 1739–1740 he studied mineralogy, metallurgy, and mining at Bergrat Henckel's laboratories in Freiberg, Saxony; there he intensified his studies of German literature. Lomonosov quickly mastered the German language, and in addition to philosophy, seriously studied chemistry, discovered the works of 17th century Irish theologian and natural philosopher, Robert Boyle, and even began writing poetry. He also developed an interest in German literature. He is said to have especially admired Günther. His Ode on the Taking of Khotin from the Turks, composed in 1739, attracted a great deal of attention in Saint Petersburg. Lomonosov returned to Russia in 1741. A year later he was named adjutant to the Russian Academy of Science in the physics department. Lomonosov was made a full member of the Academy, and named professor of chemistry, in 1745. He established the Academy's first chemistry laboratory. Eager to improve Russia’s educational system, in 1755, Lomonosov joined his patron Count Ivan Shuvalov in founding Moscow University. In 1761, he was elected a foreign member of the Royal Swedish Academy of Sciences. In 1764, Lomonosov was appointed to the position of secretary of state. In 1756, Lomonosov tried to replicate Robert Boyle's experiment of 1673. He concluded that the commonly accepted phlogiston theory was false. Anticipating the discoveries of Antoine Lavoisier, he wrote in his diary: "Today I made an experiment in hermetic glass vessels in order to determine whether the mass of metals increases from the action of pure heat. The experiments– of which I append the record in 13 pages – demonstrated that the famous Robert Boyle was deluded, for without access of air from outside the mass of the burnt metal remains the same". That is the Law of Mass Conservation in chemical reaction, which was well-known today as "in a chemical reaction, the mass of reactants is equal to the mass of the products." Lomonosov, together with Lavoisier, is regarded as the one who discovered the law of mass conservation. He stated that all matter is composed of corpuscles – molecules that are "collections" of elements – atoms. In his dissertation "Elements of Mathematical Chemistry" (1741, unfinished), the scientist gives the following definition: "An element is a part of a body that does not consist of any other smaller and different bodies ... corpuscle is a collection of elements forming one small mass." In a later study (1748), he uses term "atom" instead of "element", and "particula" (particle) or "molecule" instead of "corpuscle". He regarded heat as a form of motion, suggested the wave theory of light, contributed to the formulation of the kinetic theory of gases, and stated the idea of conservation of matter in the following words: "All changes in nature are such that inasmuch is taken from one object insomuch is added to another. So, if the amount of matter decreases in one place, it increases elsewhere. This universal law of nature embraces laws of motion as well, for an object moving others by its own force in fact imparts to another object the force it loses" (first articulated in a letter to Leonhard Euler dated 5 July 1748, rephrased and published in Lomonosov's dissertation "Reflexion on the solidity and fluidity of bodies", 1760). Lomonosov was the first person to record the freezing of mercury. Believing that nature is subject to regular and continuous evolution, he demonstrated the organic origin of soil, peat, coal, petroleum and amber. In 1745, he published a catalogue of over 3,000 minerals, and in 1760, he explained the formation of icebergs. In 1763 he published On the Strata of the Earth - his most significant geological work. TEXT 4 Dmitri Ivanovich Mendeleev 8945 п.з. Dmitri Ivanovich Mendeleev (8 February 1834 – 2 February 1907) was a Russian chemist and inventor. He formulated the Periodic Law, created a farsighted version of the periodic table of elements, and used it to correct the properties of some already discovered elements and also to predict the properties of eight elements yet to be discovered. Mendeleev was born in the village of Verkhnie Aremzyani, near Tobolsk in Siberia, to Ivan Pavlovich Mendeleev and Maria Dmitrievna Mendeleeva (née Kornilieva). His father was a teacher of fine arts, politics and philosophy. Unfortunately for the family's financial well being, his father became blind and lost his teaching position. His mother was forced to work and she restarted her family's abandoned glass factory. At the age of 13, after the passing of his father and the destruction of his mother's factory by fire, Mendeleev attended the Gymnasium in Tobolsk. In 1849, his mother took Mendeleev across Russia from Siberia to Moscow with the aim of getting Mendeleev a higher education. The university in Moscow did not accept him. The mother and son continued to Saint Petersburg to the father’s alma mater. The now poor Mendeleev family relocated to Saint Petersburg, where he entered the Main Pedagogical Institute in 1850. After graduation, he contracted tuberculosis, causing him to move to the Crimean Peninsula on the northern coast of the Black Sea in 1855. While there, he became a science master of the Simferopol gymnasium №1. In 1857, he returned to Saint Petersburg with fully restored health. Between 1859 and 1861, he worked on the capillarity of liquids and the workings of the spectroscope in Heidelberg. Later in 1861, he published a textbook named Organic Chemistry. This won him the Demidov Prize of the Petersburg Academy of Sciences. Mendeleev became a professor at the Saint Petersburg Technological Institute and Saint Petersburg State University in 1864, and 1865, respectively. In 1865 he became Doctor of Science for his dissertation "On the Combinations of Water with Alcohol". He achieved tenure in 1867 at St. Petersburg University and started to teach inorganic chemistry, while succeeding Voskresenskii to this post. By 1871 he had transformed Saint Petersburg into an internationally recognized center for chemistry research. Though Mendeleev was widely honored by scientific organizations all over Europe, including (in 1882) the Davy Medal from the Royal Society of London (which later also awarded him the Copley Medal in 1905), he resigned from Saint Petersburg University on 17 August 1890. He was elected a Foreign Member of the Royal Society in 1892, and in 1893 he was appointed director of the Bureau of Weights and Measures, a post which he occupied till his death. Mendeleev also investigated the composition of petroleum, and helped to found the first oil refinery in Russia. He recognized the importance of petroleum as a feedstock for petrochemicals. He is credited with a remark that burning petroleum as a fuel "would be akin to firing up a kitchen stove with bank notes." In 1905, Mendeleev was elected a member of the Royal Swedish Academy of Sciences. The following year the Nobel Committee for Chemistry recommended to the Swedish Academy to award the Nobel Prize in Chemistry for 1906 to Mendeleev for his discovery of the periodic system. The Chemistry Section of the Swedish Academy supported this recommendation. The Academy was then supposed to approve the Committee's choice, as it has done in almost every case. Unexpectedly, at the full meeting of the Academy, a dissenting member of the Nobel Committee, Peter Klason, proposed the candidacy of Henri Moissan whom he favored. Svante Arrhenius, although not a member of the Nobel Committee for Chemistry, had a great deal of influence in the Academy and also pressed for the rejection of Mendeleev, arguing that the periodic system was too old to acknowledge its discovery in 1906. According to the contemporaries, Arrhenius was motivated by the grudge he held against Mendeleev for his critique of Arrhenius's dissociation theory. After heated arguments, the majority of the Academy voted for Moissan. The attempts to nominate Mendeleev in 1907 were again frustrated by the absolute opposition of Arrhenius. * * * After becoming a teacher in 1867, Mendeleev wrote the definitive textbook of his time: Principles of Chemistry (two volumes, 1868–1870). It was written as he was preparing a textbook for his course. This is when he made his most important discovery. As he attempted to classify the elements according to their chemical properties, he noticed patterns that led him to postulate his periodic table. On 6 March 1869, Mendeleev made a formal presentation to the Russian Chemical Society, titled The Dependence between the Properties of the Atomic Weights of the Elements, which described elements according to both atomic weight and valence. This presentation stated that The elements, if arranged according to their atomic weight, exhibit an apparent periodicity of properties. Elements which are similar regarding their chemical properties either have similar atomic weights (e.g., Pt, Ir, Os) or have their atomic weights increasing regularly (e.g., K, Rb, Cs). The arrangement of the elements in groups of elements in the order of their atomic weights corresponds to their so-called valencies, as well as, to some extent, to their distinctive chemical properties; as is apparent among other series in that of Li, Be, B, C, N, O, and F. The elements which are the most widely diffused have small atomic weights. The magnitude of the atomic weight determines the character of the element, just as the magnitude of the molecule determines the character of a compound body. We must expect the discovery of many yet unknown elements–for example, two elements, analogous to aluminium and silicon, whose atomic weights would be between 65 and 75. The atomic weight of an element may sometimes be amended by knowledge of those of its contiguous elements. Thus the atomic weight of tellurium must lie between 123 and 126, and cannot be 128. (Tellurium's atomic mass is 127.6, and Mendeleev was incorrect in his assumption that atomic mass must increase with position within a period.) Certain characteristic properties of elements can be foretold from their atomic weights. Mendeleev published his periodic table of all known elements and predicted several new elements to complete the table in a Russian-language journal. Only a few months after, Meyer published a virtually identical table in a German-language journal. Some consider Meyer and Mendeleev the co-creators of the periodic table. Mendeleev has the distinction of accurately predicting of the qualities of what he called ekasilicon, ekaaluminium and ekaboron (germanium, gallium and scandium, respectively).The original draft made by Mendeleev would be found years later and published under the name Tentative System of Elements. Mendeleev made other important contributions to chemistry. The Russian chemist and science historian Lev Chugaev has characterized him as "a chemist of genius, first-class physicist, a fruitful researcher in the fields of hydrodynamics, meteorology, geology, certain branches of chemical technology (explosives, petroleum, and fuels, for example) and other disciplines adjacent to chemistry and physics, a thorough expert of chemical industry and industry in general, and an original thinker in the field of economy." Mendeleev was one of the founders, in 1869, of the Russian Chemical Society. He worked on the theory and practice of protectionist trade and on agriculture. Mendeleev devoted much study and made important contributions to the determination of the nature of such indefinite compounds as solutions. In another department of physical chemistry, he investigated the expansion of liquids with heat, and devised a formula similar to Gay-Lussac's law of the uniformity of the expansion of gases, while in 1861 he anticipated Thomas Andrews' conception of the critical temperature of gases by defining the absolute boiling-point of a substance as the temperature at which cohesion and heat of vaporization become equal to zero and the liquid changes to vapor, irrespective of the pressure and volume. Mendeleev is given credit for the introduction of the metric system to the Russian Empire. He invented pyrocollodion, a kind of smokeless powder based on nitrocellulose. This work had been commissioned by the Russian Navy, which however did not adopt its use. In 1892 Mendeleev organized its manufacture. Mendeleev studied petroleum origin and concluded hydrocarbons are abiogenic and form deep within the earth. He wrote: "The capital fact to note is that petroleum was born in the depths of the earth, and it is only there that we must seek its origin." (Dmitri Mendeleev, 1877) |