Таблица 3
Химическая формула
|
Константа нестойкости
|
[HgCl4]2-
|
8,510-16
|
[HgBr4]2-
|
1,010-21
|
[HgI4]2-
|
1,510-30
|
[Hg(CN)4]2-
|
4,010-42
|
[Ag(NH3)2]+
|
9,310-8
|
[Ag(NO2)2]-
|
1,310-3
|
[Ag(S2O3)2]3-
|
1,110-13
|
[Ag(CN)2]-
|
1,110-21
|
[Cu(NH 3)4]2+
|
2,110-13
|
[Cu(CN)4]2-
|
9,610-29
|
[Ni(NH 3)4]2+
|
9,110-8
|
[Ni(CN)4]2-
|
1,010-31
|
Примечание. Перечисленные ионы в водной среде более устойчивы, чем соответствующие им аквакомплексы.
Таблица 4
Стандартные электродные потенциалы Е0 некоторых металлов (ряд напряжений)
Электрод
|
Е0,B
|
Электрод
|
Е0,B
|
Li+/Li
|
-3,045
|
Ni2+/Ni
|
-0,25
|
K+/K
|
-2,924
|
Sn2+/Sn
|
-0,136
|
Ba2+/Ba
|
-2,90
|
Pb2+/Pb
|
-0,127
|
Ca2+/Ca
|
-2,87
|
Fe3+/Fe
|
-0,037
|
Na+/Na
|
-2,714
|
2H+/H2
|
0,000
|
Mg2+/Mg
|
-2,37
|
Sb3+/Sb
|
+0,20
|
Al3+/Al
|
-1,70
|
Bi3+/Bi
|
+0,215
|
Ti2+/Ti
|
-1,603
|
Cu2+/Cu
|
+0,34
|
Mn2+/Mn
|
-1,18
|
Cu+/Cu
|
+0,52
|
Cr2+/Cr
|
-0,913
|
Hg22+/2Hg
|
+0,79
|
Zn2+/Zn
|
-0,763
|
Ag+/Ag
|
+0,80
|
Cr3+/Cr
|
-0,74
|
Hg2+/Hg
|
+0,85
|
Fe2+/Fe
|
-0,44
|
Pt2+/Pt
|
+1,19
|
Cd2+/Cd
|
-0,403
|
Au3+/Au
|
+1,50
|
Co2+/Co
|
-0,277
|
Au+/Au
|
+1,70
|
Таблица 6
Значения электроотрицательностей (χ,  ) и энергий диссоциаций (D, эВ) гомоатомных ковалентных связей атомов щелочных металлов и галогенов
-
Щелочной металл
|
χ
|
D
|
 Галоген
|
χ
|
D
|
Li
Na
K
Rb
Cs
|
0,98
0,85
0,81
0,77
0,65
|
1,14
0,75
0,53
0,51
0,46
|
F
Cl
Br
I
At
|
3,68
3,13
2,99
2,74
2,4
|
1,65
2,52
2,00
1,57
1,23
|
ТАБЛИЦА ВАРИАНТОВ КОНТРОЛЬНЫХ ЗАДАНИЙ
Номер
варианта
|
Номера контрольного задания
|
Номера задач, относящихся к данному заданию
|
01
|
I
II
|
1,21,41,61,81, 101,121,141, 161, 181
201, 221, 241, 261, 281, 301, 321, 341,361, 381
|
02
|
I
II
|
2, 22, 42, 62, 82, 102, 122, 142, 162, 182
202, 222, 242, 262, 282, 302, 322, 342, 362, 382
|
03
|
I
II
|
3, 23, 43, 63, 83, 103, 123, 143, 163, 183
203, 223, 243, 263, 283, 303, 323, 343, 363, 383
|
04
|
I
II
|
4, 24, 44, 64, 84, 104, 124, 144, 164, 184
204, 224, 244, 264, 284, 304, 324, 344, 364, 384
|
05
|
I
II
|
5, 25, 45, 65, 85, 105, 125, 145, 165 185
205, 225, 245, 265, 285, 305, 325, 345,365,385
|
06
|
I
II
|
6, 26, 46, 66, 86, 106, 126, 146, 166, 186
206, 226, 246, 266, 286, 306, 326, 346, 366, 386
|
07
|
I
II
|
7, 27, 47, 67, 87, 107, 127, 147, 167, 187
207, 227, 247, 267, 287, 307, 327, 347, 367, 387
|
08
|
I
II
|
8, 28, 48, 68, 88, 108, 128, 148, 168, 188
208, 228, 248, 268, 288, 308, 328, 348, 368, 388
|
09
|
I
II
|
9, 29, 49, 69, 89, 109, 129, 149, 169, 189
209, 229, 249, 269, 289, 309, 329, 349, 369, 389
|
10
|
I
II
|
10, 30, 50, 70, 90, 110, 130, 150, 170, 190
210, 230, 250, 270, 290, 310, 330, 350, 370, 390
|
11
|
I
II
|
11, 31, 51, 71, 91, 101, 131, 151, 171, 191
211, 231, 251, 271, 291, 311, 331, 351, 371, 391
|
12
|
I
II
|
12, 32, 52, 72, 92, 112, 132, 152, 172, 192
212, 232, 252, 272, 292, 312, 332, 352, 372, 392
|
13
|
I
II
|
13, 33, 53, 73, 93, 113, 133, 153, 173, 193
213, 233, 253, 273, 293, 313, 333, 353, 373, 393
|
14
|
I
II
|
14, 34, 54, 74, 94, 114, 134, 154, 174, 194
214, 234, 254, 274, 294, 314, 334, 354, 374, 394
|
15
|
I
II
|
15, 35, 55, 75, 95, 115, 135, 155, 175, 195
215, 235, 255, 275, 295, 315, 335, 355, 375, 395
|
16
|
I
II
|
16, 36, 56, 76, 96, 116, 136, 156, 176, 196
216, 236, 256, 276, 296, 316, 336, 356, 376, 396
|
17
|
I
II
|
17, 37, 57, 77, 97, 117, 137, 157, 177, 197
217, 237, 257, 277, 297, 317, 337, 357, 377, 397
|
18
|
I
II
|
18, 38, 58, 78, 98, 118, 138, 158, 178, 198
218, 238, 258, 278, 298, 318, 338, 358, 378, 398
|
19
|
I
II
|
19, 39, 59, 79, 99, 119, 139, 159, 179, 199
219, 239, 259, 279, 299, 319, 339, 359, 379, 399
|
20
|
I
II
|
20, 40, 60, 80, 100, 120, 140, 160, 180, 200
220, 240, 260, 280, 300, 320, 340, 360, 380, 400
|
21
|
I
II
|
1, 22, 43, 64, 85, 106, 127, 148, 169, 190
211, 222, 243, 264, 285, 306, 327, 348, 381, 391
|
22
|
I
II
|
2, 23, 44, 65, 86, 107, 128, 149, 170, 191
212, 223, 244, 265, 286, 307, 328, 349, 382, 392
|
23
|
I
II
|
3, 24, 45, 66, 87, 108, 129, 150, 171, 192
213, 224, 245, 266, 287, 308, 329, 350, 383, 393
|
24
|
I
11
|
4, 25, 46, 67, 88, 109, 130, 151, 172, 193
214, 225, 246, 267, 288, 309, 330, 351, 384, 394
|
25
|
I
II
|
5, 26, 47, 68, 89, 110, 131, 152, 173, 194
215, 226, 247, 268, 289, 310, 331, 352, 385, 395
|
26
|
I
II
|
6, 27, 48, 69, 90, 111, 132, 153, 174, 195
216, 227, 248, 269, 290, 311, 332, 353, 386,396
|
27
|
I
II
|
7, 28, 49, 70, 91, 112, 133, 154, 175, 196
217, 228, 249, 270, 291, 312, 333, 354, 387, 397
|
28
|
I
II
|
8, 29, 50, 71, 92, 113, 134, 155, 176, 197
218, 229, 250, 271, 292, 313, 334, 355, 388, 398
|
29
|
I
II
|
9, 30, 51, 72, 93, 114, 135, 156, 177, 198
219, 230, 251, 272, 293, 314, 335, 356, 389, 399
|
30
|
I
II
|
10, 31, 52, 73, 94, 115, 136, 157, 178, 199
220, 231, 252, 273, 294, 315, 336, 357, 390,400
|
31
|
I
II
|
11, 32, 53, 74, 95, 116, 137, 158, 179, 200
201, 232, 253, 274, 295, 316, 337, 358, 361, 381
|
32
|
I
11
|
12, 33, 54, 75, 96, 117, 138, 159, 180, 181
202, 233, 254, 275, 296, 317, 338, 359, 362,382
|
33
|
I
II
|
13, 34, 55, 76, 97, 118, 139, 160, 161, 182
203, 234, 255, 276, 297, 318, 339, 360, 363,383
|
34
|
I
II
|
14, 35, 56, 77, 98, 119, 140, 141, 162, 183
204, 235, 256, 277, 298, 319, 340, 347, 364, 384
|
35
|
I
II
|
15, 36, 57, 78, 99, 120, 121, 142, 163, 184
205, 236, 257, 278, 299, 320, 322, 346,365, 385
|
36
|
I
II
|
16, 37, 58, 79, 100, 101, 122, 143, 164, 185
206, 237, 258, 279, 300, 301, 323, 345, 366, 386
|
37
|
I
II
|
17, 38, 59, 80, 81, 102, 123, 144, 165, 186
207, 238, 259, 280, 281, 302, 324, 344, 367, 387
|
38
|
I
II
|
18, 39, 60, 65, 86, 107, 128, 145, 166, 187
208, 239, 260, 261, 282, 303, 325, 343, 368, 388
|
39
|
I
II
|
19, 40, 44, 66, 87, 108, 129, 146, 167, 188
209, 240, 241, 262, 283, 304, 326, 342, 369, 389
|
40
|
I
II
|
20, 23, 45, 67, 88, 109, 130, 147, 168, 189
210, 221, 242, 263, 284, 305, 327, 341, 370, 390
|
41
|
I
II
|
2, 24, 46, 68, 89, 110, 131, 148, 170, 190
201, 223, 241, 265, 281, 306, 328, 341, 371, 391
|
42
|
I
II
|
3, 25, 47, 69, 90, 111, 132, 149, 171, 191
202, 224, 242, 266, 282, 307, 329, 342,372, 392
|
43
|
I
II
|
4, 26, 48, 70, 91, 112, 133, 150, 172, 192
203, 225, 243, 267, 283, 308, 330, 343, 373, 393
|
44
|
I
II
|
5, 27, 49, 71, 92, 113, 134. 151, 173, 193
204, 226, 244, 268, 284, 309, 331, 344, 374, 394
|
45
|
I
II
|
6, 28, 50, 72, 93, 1 14, 135, 152, 174, 194
205, 227, 245, 269, 285, 310, 332, 345, 375, 395
|
46
|
I
II
|
7, 29, 51, 73, 94, 115, 136, 153, 175, 195
206, 228, 246, 270, 286, 311, 333, 346, 376, 396
|
47
|
I
II
|
8, 30, 52, 74, 95, 116, 137, 154, 176, 196
207, 229, 247, 271, 287, 312, 334, 347, 377, 397
|
48
|
I
II
|
9, 31, 53, 75, 96, 117, 138, 155, 177, 197
208, 230, 248, 272, 288, 313, 335, 348, 378, 398
|
49
|
I
11
|
10, 32, 54, 76, 97, 118, 139, 156, 178, 198
209, 231, 249, 273, 289, 314, 336, 349, 379, 399
|
50
|
I
II
|
11, 33, 56, 77, 98, 119, 140, 157, 179, 199
210, 232, 250, 274, 290, 315, 337, 350, 380, 400
|
51
|
I
II
|
12, 34, 56, 78, 99, 120, 122, 158, 180, 200
211, 233, 251, 275, 291, 316, 321, 351, 361, 390
|
52
|
I
II
|
13, 35, 57, 79, 100, 103, 121, 159, 169, 182
212, 234, 252, 276, 292, 317, 325, 352, 362, 389
|
53
|
I
II
|
14, 36, 58, 80, 85, 104, 123, 160, 161, 183
213, 235, 253, 277, 293, 318, 324, 353, 363, 388
|
54
|
I
II
|
15, 37, 59, 61, 84, 105, 124, 141, 162, 184
214, 236, 254, 278, 294, 319, 323, 354, 364, 387
|
55
|
I
II
|
16, 38, 60, 62, 83, 106, 125, 143, 163, 185
215, 237, 255, 279, 295, 320, 322, 355, 365, 386
|
56
|
I
II
|
17, 33, 41, 63, 82, 101, 126, 142, 164, 186
216, 238, 256, 280, 296, 301, 321, 356, 366, 385
|
57
|
I
II
|
18, 40, 42, 61, 81, 102, 127, 144, 165, 187
217, 239, 257, 271, 297, 302, 326, 357, 367, 384
|
58
|
1
II
|
19, 21, 43, 62, 87, 103, 128, 145, 166, 188
218, 240, 258, 272, 298, 303, 327, 358, 368, 383
|
59
|
I
II
|
20, 22, 41, 63, 88, 104, 129, 146, 167, 189
219, 223, 259, 273, 299, 304, 328, 359, 369, 382
|
60
|
I
II
|
1, 24, 42, 64, 89, 105, 130, 147, 168, 190
220, 222, 260, 274, 300, 305, 329, 360, 370, 381
|
61
|
I
II
|
3, 25, 43, 65, 90, 106, 131, 148, 169, 191
201, 221, 250, 275, 281, 301, 330, 341, 361, 392
|
62
|
I
II
|
4, 26, 44, 66, 91, 107, 132, 149, 170, 192
202, 222, 251, 276, 282, 302, 331, 342, 362, 393
|
63
|
I
II
|
5, 27, 45, 67, 92, 108, 133, 150, 171, 193
203, 224, 252, 277, 283, 303, 332, 343, 363, 394
|
64
|
I
II
|
6, 28, 46, 68, 93, 109, 134, 151, 172, 194
204, 223, 253, 278, 284, 304, 333, 344, 364, 395
|
65
|
I
II
|
7, 29, 47, 69, 94, 110, 135, 152, 173, 195
205, 225, 254, 279, 285, 305, 334, 345, 365, 396
|
66
|
I
II
|
8, 30, 48, 70, 95, 111,136, 153,174, 196
206, 226, 255, 280, 286, 306, 335, 346, 366, 397
|
67
|
I
II
|
9, 31, 49, 71, 96, 112, 137, 154, 175, 197
207, 227, 256, 261, 287, 307, 336, 347, 367, 398
|
68
|
I
II
|
10, 32, 50, 72, 97, 113, 138, 155, 176, 198
208, 228, 257, 262, 288, 308, 337, 348, 368, 399
|
69
|
I
II
|
11, 33, 51, 73, 98, 114, 139, 156, 177, 199
209, 229, 258, 263, 289, 309, 338, 349, 369, 400
|
70
|
I
II
|
12, 34, 52, 74, 99, 1 15, 140, 157, 178, 200
210, 230, 259, 264, 290, 310, 339, 350, 370, 381
|
71
|
I
II
|
13, 35, 53, 75, 100, 116, 121, 158, 178, 181
211, 231, 260, 265, 291, 31 1, 340, 351, 371, 381
|
72
|
I
II
|
14, 36, 54, 76, 86, 1 17, 122, 159, 180, 182
212, 232, 241, 266, 292, 312, 321, 352, 372, 382
|
73
|
I
II
|
15, 37, 55, 77, 85, 118, 123, 160, 162, 183
213, 233, 242, 267, 293, 313, 322, 353, 373, 383
|
74
|
I
II
|
16, 38, 56, 78, 84, 1 19, 124, 142, 161, 184
214, 234, 243, 268, 294, 314, 323, 354, 374, 384
|
75
|
I .
II
|
17, 39, 57, 79, 83, 120, 125, 141, 163, 185
215, 235, 244, 269, 295, 315, 324, 355, 375, 385
|
76
|
I
II
|
18, 40, 58, 80, 82, 101, 126, 143, 164, 186
216, 236, 245, 270, 296, 316, 325, 356, 376, 386
|
77
|
I
II
|
19, 23, 59, 61, 81, 102, 127, 144, 165, 187
217, 237, 246, 271, 297, 317, 326, 357, 377, 387
|
78
|
I
II
|
20, 21, 60, 62, 100, 103, 128, 145, 166, 188
218, 238, 247, 272, 298, 318, 327, 358, 378, 388
|
79
|
I
II
|
4, 22, 51, 63, 99, 104, 129, 146, 167, 189
219, 239, 248, 273, 300, 319, 328, 359, 379, 389
|
80
|
I
II
|
5, 23, 52, 64, 98, 105, 130, 147, 168, 190
220, 240, 249, 274, 281, 320, 329, 360, 380, 390
|
81
|
I
II
|
6, 24, 53, 65, 97, 106, 131, 148, 169, 191
211, 231, 250, 275, 282, 301, 330, 351, 381, 392
|
82
|
I
II
|
7, 25, 54, 66, 96, 107, 132, 149, 170, 192
212, 232, 251, 276, 283, 302, 334, 352, 382, 393
|
83
|
I
II
|
8, 26, 55, 67, 95, 108, 133, 150, 171, 193
213, 233, 252, 277, 284, 303, 335, 353, 383, 394
|
84
|
I
II
|
9, 27, 56, 68, 94, 109, 134, 151, 172, 194
214, 234, 253, 278, 285, 304, 336, 354, 384, 395
|
85
|
I
II
|
10, 28, 57, 69, 93, 110, 135, 152, 173, 195
215, 235, 254, 279, 286, 305, 337, 355, 385, 396
|
86
|
I
II
|
11, 29, 58, 70, 92, 111, 136, 153, 174, 196
216, 236, 255, 280, 287, 306, 338, 356, 386, 397
|
87
|
I
II
|
12, 30, 59, 71, 91, 112, 137, 154, 175, 197
217, 237, 256, 264, 288, 307, 339, 357, 387, 398
|
88
|
I
II
|
13 ,31, 60, 72 ,90, 113, 138, 155, 176, 198
218, 238, 257, 265, 289, 308, 340, 358, 388, 399
|
89
|
I
II
|
14, 32, 41, 73, 89, 114, 139, 156, 177, 199
219, 239, 258, 266, 290, 309, 331, 359, 389, 400
|
90
|
I
II
|
15, 33, 42, 74, 88, 115, 140, 157, 178, 200
220, 240, 259, 267, 291, 310, 332, 360, 379, 381
|
91
|
I
II
|
16, 34, 43, 75, 87, 116, 131, 158, 179, 181
201, 221, 260, 268, 292, 311, 333, 341, 378 382
|
92
|
I
II
|
17, 35, 44, 76, 86, 117, 132, 159, 180, 182
202, 222, 241, 269, 293, 312, 321, 342, 377, 383
|
93
|
I
II
|
18, 36, 45, 77, 85, 1 18, 133, 160, 161, 183
203, 223, 242, 270, 294, 313, 322, 343, 376, 384
|
95
|
I
II
|
19, 37, 46, 78, 84, 119, 134, 141, 162, 184
204, 224, 243, 261, 295, 314, 323, 344, 375, 385
|
95
|
I
II
|
20, 38, 47, 79, 83, 120, 135, 142, 163, 185
205, 225, 244, 262, 296, 315, 324, 345, 374, 386
|
96
|
I
II
|
1, 39, 48, 80, 82, 110, 136, 143, 164, 186
206, 226, 245, 263, 297, 316, 325, 346, 373, 387
|
97
|
I
II
|
2, 40, 49, 61, 81, 111, 137, 144, 165, 187
207, 227, 246, 271, 298, 317, 326, 347,372, 388
|
98
|
I
II
|
3, 24, 50, 62, 100, 112, 138, 145, 166, 188
208, 228, 247, 272, 299, 318, 327, 348, 371, 389
|
99
|
I
II
|
4, 25, 51, 63, 99, 113, 139, 146, 167, 189
209, 229, 248, 273, 300, 319, 328, 349, 370, 390
|
00
|
1
II
|
5, 26, 52, 64, 98, 114, 140, 147, 168, 190
210, 230, 249, 274, 281, 320, 329, 350, 369, 391
|
СОДЕРЖАНИЕ
Общие положения по выполнению контрольных работ……………………….. 3
Оформление контрольных работ………………………………………………… 3
Программа для подготовки к экзаменам по химии…………………………….. 4
Список рекомендуемой литературы…………………………………………….. 5
Основная часть (содержит примеры решения типовых задач с кратким тео-ретическим введением в содержание разделов курса химии и контрольные
задания для студентов)……………………………………………………………. 7
Приложение (6 таблиц для выполнения контрольных работ)…………………. 90
Таблица вариантов контрольных заданий………………………………………………… 95
|
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